Selective TEMPO-Mediated Oxidation of Thermomechanical Pulp
نویسندگان
چکیده
منابع مشابه
Selective TEMPO-Mediated Oxidation of Thermomechanical Pulp
Carboxylic acid groups were introduced onto thermomechanical pulp (TMP) long fiber surfaces by 2,2,6,6,tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation in the present study. The number of introduced carboxylic groups was closely related to the NaClO dosage, and more flexible fibers with lower curl and kink index were generated. Lignin was dissolved during the TEMPO-mediated oxida...
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The oxidation of natural polysaccharides by TEMPO has become by now an "old chemical reaction" which led to numerous studies mainly conducted on cellulose. This regioselective oxidation of primary alcohol groups of neutral polysaccharides has generated a new class of polyuronides not identified before in nature, even if the discovery of enzymes promoting an analogous oxidation has been more rec...
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TEMPO-mediated oxidation has been reported to effectively convert C6 primary hydroxyl groups to carboxyl groups for better water-solubility. However, the pH decreases continuously during the oxidation process, and it is therefore difficult to maintain the stability of the reaction. The control of pH at a constant level throughout the oxidation process is a complicated task. The applicability of...
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The electrocatalytic oxidation of alcohols mediated by TEMPO-like nitroxyl radicals is an economically and industrially viable method that will shortly find commercial application in the synthesis of valued substances including active pharmaceutical ingredients (APIs), valued natural product derivatives, fine chemicals, and valued nanomaterials.
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Hypervalent iodine(III)/TEMPO-mediated oxidation of various aliphatic, aromatic and allylic alcohols to their corresponding carbonyl compounds was successfully achieved by using microreactor technology. This method can be used as an alternative for the oxidation of various alcohols achieving excellent yields and selectivities in significantly shortened reaction times.
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ژورنال
عنوان ژورنال: BioResources
سال: 2013
ISSN: 1930-2126
DOI: 10.15376/biores.8.3.4396-4405